Large-pore hydrodemetallization catalyst and process...

B - Operations – Transporting – 01 – J

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252/101, 196/133

B01J 23/24 (2006.01) B01J 35/10 (2006.01) C10G 45/04 (2006.01)

Patent

CA 1104115

LARGE-PORE HYDRODEMETALLIZATION CATALYST AND PROCESS EMPLOYING SAME Abstract of the Invention There is disclosed a catalyst for the hydrodemetallization of petroleum hydrocarbon streams containing asphaltenes and large quanti- ties of metals. This catalyst consists essentially of a small amount of a single hydrogenation metal selected from the group consisting of metals from Group VIB of the Periodic Table of Elements and metals from Group VIII of the Periodic Table deposed on a large-pore alumina. The hydrogenation metal may be present in the elemental form, as an oxide, as a sulfide, or mixtures thereof. The catalyst is characterized by a surface area of at least 120 square meters per gram, a pore volume of at least 0.7 cc per gram, and an average pore diameter of at least 125 Angstrom units. Suitable examples of a hydrogenation metal are nickel and molybdenum. Also disclosed is a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals, which process comprises contacting said hydrocarbon stream in a reaction zone under suitable operating conditions and in the presence of hydrogen with the catalyst described hereinabove.

305761

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