Layered compounds of mixed oxides and lewis bases

Details Layered compounds of mixed oxides and lewis bases Layered compounds of mixed oxides and lewis bases

C - Chemistry, Metallurgy

09

K

31/1, 31/153

C09K 3/00 (2006.01) C07F 9/02 (2006.01) C07F 9/58 (2006.01) C08G 79/14 (2006.01)

Patent

CA 1164644

ABSTRACT OF THE DISCLOSURE A new composition of matter comprising the re- action product of a mixed oxide having layers of corner linked octahedra and tetrahedra and a Lewis base. The reaction product forms a layered compound of the formula LXMOM'O4 where MOM'O4 is a mixed oxide selected from the group consisting of VOPO4, VOSO4, VOAsO4, VOMoO4, NbOPO4, NbOAsO4, TaOPO4 and MoOPO4, x is from about 0.1 to 1.0 and L is a Lewis base containing nitrogen or oxygen electron donor and is selected from the group consisting of 5-mem- bered heterocyclic amines, 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides. The layered compounds are characterized in that L is covalently bound to a metal atom in the MOM'O4 layer.

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