Leaching of sulphidic mattes containing non-ferrous metals...

C - Chemistry – Metallurgy – 22 – B

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C22B 3/00 (2006.01) C22B 3/08 (2006.01)

Patent

CA 1152337

A B S T R A C T A method of treating sulphidic mattes containing from 5% to 60% iron; from 15% to 90% sulphur together with soluble non-ferrous metals such as copper, cobalt, nickel and zinc and also optionally insoluble non-ferrous metals which term includes platinum group metals gold and silver by a leaching process to effect substantial separation of the non-ferrous metals from iron as well as from insoluble residue material. The matte is contacted in a finely subdivided form with sulphate in acid medium at a temperature of from 70°C to 120°C and an oxygen partial pressure of from 50kPa to 1,000kPa. The quantity of sulphate present is at least the stoichiometric amount required for dissolving the soluble non-ferrous metals present but is limited to ensure that a substantial proportion of iron which dissolves simultaneously with the soluble non-ferrous metals precipitates out as it is replaced by dissolving non-ferrous metals.

371041

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