Li-exchanged low silica emt-containing metallosilicates

C - Chemistry – Metallurgy – 01 – B

Patent

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C01B 39/20 (2006.01) B01D 53/04 (2006.01) B01D 53/047 (2006.01) B01J 20/18 (2006.01) C01B 13/02 (2006.01) C01B 21/04 (2006.01)

Patent

CA 2148893

The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula: (0 20-0.0)M2/no:(0.80-1.0)Li2O:X2O3:(2.0 to <4.0)SiO2 wherein M = a metal cation other than lithium having a valence of n, and X is selected from the group consisting of aluminum, gallium and boron, preferably aluminum.

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