Linear trimer of para-isopropenyl phenol and process for its...

C - Chemistry – Metallurgy – 07 – C

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C07C 39/12 (2006.01) C07C 37/11 (2006.01) C07C 37/14 (2006.01) C07C 37/52 (2006.01) C07C 39/21 (2006.01) C07D 303/24 (2006.01) C08G 59/32 (2006.01) C08G 59/62 (2006.01)

Patent

CA 1097692

Abstract of the Disclosure A novel trimer of p-isopropenyl phenol of the structure Image which is useful as a material or a curing agent for epoxy resins. The linear trimer includes a cis-isomer (m.p. 225.5 - 227°C) and a trans-isomer (m.p. 167 - 168°C). It is prepared by reacting p-isopropenyl phenol or its linear polymer in the presence of an acid catalyst such as sulfuric acid, boron fluoride or activated clay in an aromatic hydrocarbon, halogenated hydrocarbon, substituted aromatic hydrocarbon or aprotic polar solvent (e.g., benzene, carbon tetrachloride, nitrobenzene or dioxane).

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