Liquid injection of vcl4 into superheated ticl4 for the...

C - Chemistry – Metallurgy – 22 – C

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C22C 1/00 (2006.01) B22F 9/00 (2006.01) C22C 14/00 (2006.01)

Patent

CA 2672300

A method and system for producing an alloy using a flowing stream of superheated halide vapor to flash vaporize liquid halides forming a mixture of gases in predetermined and controllable ratios. The mixture of gases are introduced into a flowing stream of liquid alkali or alkaline earth metal or mixtures to establish a reaction zone where the mixture of gases is reduced to an alloy and a salt. The liquid metal is in a sufficient amount in excess of stoichiometric to maintain substantially all the alloy and salt below the sintering temperatures thereof away from the reaction zone. Equipment for practicing the method is also disclosed. The system relates to alloys of B, Be, Bi, C, Fe, Ga, Ge, Hf, In, Mo, Nb, P, Pb, Re, S, Sb, Si, Sn, Ta, Ti, V, W and Zr.

La présente invention concerne un procédé et un système permettant de produire un alliage mettant en AEuvre un écoulement fluide de vapeur d'halogénure surchauffée pour la vaporisation-éclair de d'halogénures liquides formant un mélange de gaz dans des rapports prédéterminés et contrôlables. Le mélange des gaz est introduit dans un écoulement fluide d'alcali liquide ou de métal alcalino-terreux ou leurs mélanges pour établir une zone de réaction où le mélange de gaz est réduit en un alliage et un sel. Le métal liquide est en quantité suffisante dépassant la quantité stoechiométrique pour maintenir sensiblement l'ensemble d'alliage et de sel en-dessous de leurs températures de frittage éloignés de la zone de réaction. L'invention concerne également un matériel pour la mise en AEuvre du procédé. Le système concerne des alliages de B, Be, Bi, C, Fe, Ga, Ge, Hf, In, Mo, Nb, P, Pb, Re, S, Sb, Si, Sn, Ta, Ti, V, W et Zr.

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