Lithium ion batteries employing boron treated graphite...

H - Electricity – 01 – M

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H01M 10/26 (2006.01) H01M 4/58 (2006.01) H01M 6/10 (2006.01) H01M 10/40 (2006.01)

Patent

CA 2198417

Highly graphitic carbons with average d002 spacings less than 3.37 .ANG. are desirable as high capacity anode materials for non-aqueous rechargeable lithium ion batteries. However, such graphitic anodes are incompatible with certain common electrolyte solvents, including propylene carbonate. Unexpectedly, boron treated, but otherwise similar, graphitic carbon anodes can be compatible with these solvents. Boron treatment can be additionally used to further glaphitize the carbon anode.

Les carbones hautement graphitiques ayant des espacements moyens d002 inférieurs à 3,37 angstroms sont recherchés comme matières anodiques de capacité élevée pour les accumulateurs aux ions de lithium non aqueux rechargeables. Cependant, ces anodes graphitiques sont incompatibles avec certains solvants électrolytiques courants, dont le carbonate de propylène. De manière inattendue, les anodes de carbone graphitique traitées au bore, mais par ailleurs semblables, peuvent être compatibles avec ces solvants. Le traitement au bore peut également être utilisé pour graphitiser encore davantage l'anode de carbone.

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