Lithium/organosulfur redox cell having protective solid...

Details Lithium/organosulfur redox cell having protective solid... Lithium/organosulfur redox cell having protective solid...

H - Electricity

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H01M 10/39 (2006.01) H01M 4/12 (2006.01) H01M 4/60 (2006.01) H01M 10/36 (2006.01)

Patent

CA 2050886

LITHIUM/ORGANOSULFUR REDOX CELL HAVING PROTECTIVE SOLID ELECTROLYTE BARRIER FORMED ON ANODE AND METHOD OF MAKING SAME ABSTRACT OF THE DISCLOSURE A lithium/organosulfur redox cell is disclosed which comprises a solid lithium anode, a liquid organosulfur cathode, and a barrier layer formed adjacent a surface of the solid lithium anode facing the liquid organosulfur cath- ode consisting of a reaction product of the lithium anode with the organosulfur cathode. The organosulfur cathode comprises a material having the formula (R(S)y)N where y - 1 to 6, n = 2 to 20, and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the linear chain may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

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