Lithium primary cell, cathode active material therefor, and...

C - Chemistry – Metallurgy – 25 – B

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319/36, 204/63,

C25B 1/00 (2006.01) C25B 1/21 (2006.01) H01M 4/24 (2006.01) H01M 4/50 (2006.01) H01M 10/24 (2006.01)

Patent

CA 2004744

A lithium primary cell includes a cathode active material containing 0.05 to 2.0 parts by weight of phosphorus with respect to 100 parts by weight of manganese dioxide. A cathode active material for a lithium primary cell contains 0.05 to 2.0 parts by weight of phosphorus with respect to 100 parts by weight of manganese dioxide. A method for manufacturing electrolytic manganese dioxide comprises adding at least one member selected from the group consisting of phosphoric acid, phosphorous acid, hypophosphorous acid and compounds thereof to the electrolyte during the manufacture of electrolytic manganese dioxide using manganese sulfate and a sulfuric acid solution as the electrolyte.

Une pile primaire au lithium comprend une matière active cathodique contenant 0,05 à 2,0 parties en poids de phosphore par rapport à 100 parties en poids de dioxyde de manganèse. Une matière active cathodique pour une pile primaire au lithium contient 0,05 à 2,0 parties en poids de phosphore par rapport à 100 parties en poids de dioxyde de manganèse. Une méthode de fabrication de dioxyde de manganèse électrolytique comprend l'addition à l'électrolyte d'au moins un composé choisi dans le groupe constitué de l'acide phosphorique, de l'acide phosphoreux, de l'acide hypophosphoreux et de dérivés de ces derniers durant la fabrication de dioxyde de manganèse électrolytique en utilisant du sulfate de manganèse et une solution d'acide sulfurique comme électrolyte.

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