Long chain branching in polyolefins from ziegler- natta...

B - Operations – Transporting – 01 – J

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402/626, 252/52.

B01J 31/14 (2006.01) C07F 5/06 (2006.01) C08F 110/02 (2006.01)

Patent

CA 1225096

ABSTRACT OF THE DISCLOSURE Generally, linear polyethylene containing long chain branching is obtained by polymerizing ethylene in the presence of a catalyst comprising a transition metal compound such as titanium chloride, an organoaluminum compound represented by the formula RlR2AlRp wherein Rl & R2 are the same or different hydrocarbyl groups having from 1 to 18 carbon atoms and Rp is a polymeric hydrocarbyl group containing long chain branching and an aluminum alkyl cocatalyst.

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