Low energy process for the recovery of copper from ammonia...

B - Operations – Transporting – 22 – F

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B22F 9/00 (2006.01) B01D 3/00 (2006.01)

Patent

CA 1119816

ABSTRACT OF DISCLOSURE A process for the recovery of copper from copper bearing materials which comprises leaching the copper bearing materials with ammoniacal solutions to produce a leach solution containing copper tetra-ammine sul- phate, converting the copper tetra-ammine sulphate to a substantially ammonia free copper sulphite, dissolving the substantially ammonia free copper sulphite in a solution of copper II sulphate water and an organic nitrile comprising acetonitrile, and disproportionating the solution to precipitate copper powder.

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