Low molecular weight tert.-alcohols

C - Chemistry – Metallurgy – 07 – C

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260/639, 260/627

C07C 31/02 (2006.01) C07C 11/02 (2006.01) C08F 2/38 (2006.01)

Patent

CA 1065346

ABSTRACT OF THE DISCLOSURE Process for the telomerization of olefins with secondary alcohols comprising admixing a secondary alcohol telogen with a mono-olefinically unsaturated hydrocarbon taxogen in catalytically effective amounts of a free radical generating initiator in a reaction zone, the telogen to taxogen molar ratio in the reaction zone being greater than about 1:1 as measured on the effluent stream from the reactio zone, at a temperature ranging from about 125°C. to about 275°C. and that a pressure varying from about 2000 psi to about 10,000 psi.

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