Low-temperature hydrocarbon production from oxygenated...

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 1/20 (2006.01)

Patent

CA 2485558

Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phase conditions at acidic pHs. The disclosed method allows the production of hydrocarbon by the liquid-phase reaction of water with biomass-derived oxygenated compounds.

L'invention concerne un procédé de production d'hydrocarbures à partir de réactifs d'hydrocarbures oxygénés tels que glycérol, glucose ou sorbitol. Ce procédé peut s'effectuer au cours de la phase vapeur ou, de préférence, au cours de la phase liquide condensé. Ce procédé consiste à faire réagir l'eau et un hydrocarbure oxygéné soluble dans l'eau comprenant au moins deux atomes de carbone, en présence d'un catalyseur contenant un métal. Ledit catalyseur contient un métal sélectionné parmi le groupe constitué de métaux de transition du groupe VIIIB, et des alliages et des mélanges de ces métaux. Ces métaux sont supportés sur des supports qui présentent de l'acidité ou la réaction est conduite en états à phase liquide à pH acide. Ledit procédé permet de produire hydrocarbure par la réaction en phase liquide d'eau avec des composés oxygénés dérivés de biomasse.

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