Lubricating compositions, functional fluids and greases...

C - Chemistry – Metallurgy – 10 – M

Patent

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Details

C10M 137/04 (2006.01) C10M 137/10 (2006.01) C10M 141/10 (2006.01) C10M 141/12 (2006.01) C10M 167/00 (2006.01) C10M 169/06 (2006.01)

Patent

CA 2178692

This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbylterminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula Image wherein X1, X2, and X3 are oxygen or sulfur, provided that at least one of X1, X2, and X3 is sulfur; R1 is a hydrocarbyl group; R2 is an alkylene group; R3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester. The lubricating compositions, functional fluids and greases have improved antiwear/extreme pressure properties and improved antioxidation properties. In functional fluids, the thiophosphorus acid esters and their salts act as antiwear agents and rust inhibitors.

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