Magnetic separation of high activity catalyst from low...

C - Chemistry – Metallurgy – 10 – G

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C10G 11/05 (2006.01) C10G 11/18 (2006.01)

Patent

CA 1183795

Abstract A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650°F plus material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalent of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil to- gether with particulate cracking catalyst through a progres- sive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a pre- determined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900 to about 1400°F, and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 50% to about 90% while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.3 to about 3% by weight. The spent, coke-laden catalyst is separated from the stream of hydrocarbons formed by vaporized feed and re- sultant cracking products and regenerated in one or more regeneration beds in one or more regeneration zones by burn- ing the coke on the spent catalyst with oxygen. The re- generated catalyst is recycled to the reactor and contacted with fresh carbo-metallic oil. A portion of the catalyst is withdrawn from the cycle, passed through a magnetic field to separate the mass of catalyst into high activity catalyst and low activity catalyst, returning the high activity catalyst the cycle and disposing of the low activity catalyst.

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