Manipulation of topological characteristics of bulk...

C - Chemistry – Metallurgy – 08 – F

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C08F 10/14 (2006.01) C08F 2/00 (2006.01) C08F 255/08 (2006.01) C08J 5/16 (2006.01) C10L 1/16 (2006.01) C10L 10/16 (2006.01)

Patent

CA 2608280

The dissolution of polymeric drag reducing agents (DRAs) in flowing hydrocarbon fluids is improved by incorporating branching into the polymer DRAs. A branched polymer of the same molecular weight will have a smaller overall size because of its reduced radius of gyration (Rg), and thus dissolve more readily. In one non-limiting embodiment, the polymer is a poly(alpha- olefin) and the branches are long-chain branches (Y-branching) and/or induced or H-branching, whereby the induced branch length may have an average chain length of at least 4-8 carbon atoms.

La dissolution d'agents polymères de réduction de la résistance de frottement (DRA) dans des fluides hydrocarbures en écoulement est améliorée par l'introduction de la ramification dans les DRA polymères. Un polymère ramifié du même poids moléculaire aura une taille globale plus petite en raison de son rayon de rotation réduit (Rg), et se dissoudra donc plus facilement. Dans un mode de réalisation non restrictif, le polymère est une poly(alpha-oléfine) et les ramifications sont des ramifications à chaîne longue (ramifications en Y) et / ou des ramifications induites ou en H, les ramifications induites pouvant avoir une longueur de chaîne moyenne d'au moins 4 à 8 atomes de carbone.

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