Manufacture of copolymers of ethylene

C - Chemistry – Metallurgy – 08 – F

Patent

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402/306, 402/413

C08F 2/00 (2006.01) C08F 6/26 (2006.01) C08F 210/02 (2006.01)

Patent

CA 1100690

ABSTRACT OF THE DISCLOSURE: A process for the manufacture of co- polymers of ethylene with vinyl acetate at pressures above 800 at- mospheres and at from 150 to 350°C, using mean residence times of up to at most 100 seconds. The reaction mixture obtained from the polymerization is kept for from 2 to 10 minutes at from 150 to 250°C under a pressure below 500 atmospheres. Homogeneous ethylene/ vinyl acetate copolymers are obtained without the formation of substantial amounts of free acetic acid by decomposition of the vinyl acetate.

252137

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