Manufacture of cyclic ester oligomers

C - Chemistry – Metallurgy – 08 – G

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C08G 63/78 (2006.01) C08G 63/81 (2006.01)

Patent

CA 2437562

Cyclic ester oligomers (CEOs) are manufactured from linear polyesters or their precursors by a continuous reactive extraction in which the linear polyesters are converted to the CEOs and the CEOs selectively removed from the mixture by extraction with a fluid. The fluid may be a liquid or a gas. The CEOs prodcued are useful as monomers, for example in a reaction injection molding process to rapidly form polyesters from low viscosity liquids.

L'invention concerne un procédé de fabrication d'oligomères d'esters cycliques (CEO) à partir de polyesters linéaires ou de précurseurs de ceux-ci, par la mise en oeuvre d'une extraction réactive en continu dans laquelle les polyesters linéaires sont transformés en CEO, et les CEO sont éliminés de manière sélective du mélange par extraction à l'aide d'un fluide. Le fluide peut être un liquide ou un gaz. Les CEO produits sont utiles comme monomères, par exemple dans un procédé de moulage par injection et réaction pour former rapidement des polyesters à partir de liquides à faible viscosité.

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