Manufacture of precipitated calcium carbonate of improved...

C - Chemistry – Metallurgy – 01 – F

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C01F 11/18 (2006.01)

Patent

CA 2237960

A method for the manufacture of precipitated calcium carbonate from impure calcium oxide of improved colour is disclosed. The method comprises admixing impure calcium oxide with an aqueous solution consisting essentially of a salt of at least one compound selected from the group consisting of organic amines of the formula RNH2 and alkanolamines of the formula NH2(R1OH), where R and R1 are alkyl groups of 1-4 carbon atoms, and hydrochloric or nitric acid. The solution obtained is treated with a reducing agent e.g. sodium hydrosulphite, separated from insoluble matter and then treated with carbon dioxide or the carbonate of the amine or alkanolamine at a temperature of at least 50°C. Preferably, the amine of the salt and of the carbonate are the same, and the salt is used in at least the stoichiometric amount to dissolve the lime.

Divulgation d'un procédé pour obtenir du carbonate de calcium précipité, à couleur améliorée, à partir d'oxyde de calcium impur. Le procédé consiste à mélanger de l'oxyde de calcium impur avec une solution aqueuse constituée essentiellement d'un sel d'au moins un composé choisi dans le groupe comprenant des amines organiques de formule RNH2 et des alcanolamines de formule NH2(R1OH), où R et R1 sont des groupes alkyle de 1 à 4 atomes de carbone, ainsi que de l'acide chlorhydrique ou nitrique. La solution obtenue est traitée avec un réducteur, p. ex. l'hydrosulfite de sodium, séparée de la matière insoluble, puis traitée avec le dioxyde de carbone ou le carbonate de l'amine ou une alcanolamine à une température d'au moins 50 degrés C. L'amine du sel et du carbonate sont de préférence les mêmes, et le sel est utilisé au moins en proportion stoechiométrique pour dissoudre la chaux.

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