Material for resolution of optical isomers, its preparation...

C - Chemistry – Metallurgy – 07 – F

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260/429, 252/1.A

C07F 15/06 (2006.01) B01D 15/08 (2006.01) C07C 51/487 (2006.01) C07C 59/50 (2006.01) C08G 77/02 (2006.01)

Patent

CA 1202978

ABSTRACT MATERIAL FOR RESOLUTION OF OPTICAL ISOMERS, ITS PREPARATION AND USE. Optical isomers of an optically active compound can be resolved by contact with a material comprising macromolecular silicon dioxide and molecules of a resolved optically active form of a cobalt(III) complex. The complex has six amino nitrogen atoms coordinated thereto and the cobalt(III) complex molecules are covalently bonded to the macromolecular silicon dioxide through bridging chains. The material is prepared from functionalized silicon dioxide and a labile cobalt(III) complex.

431505

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