Measurement device for determining oxygen activity in metal...

G - Physics – 01 – N

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G01N 27/26 (2006.01) G01N 27/30 (2006.01) G01N 27/411 (2006.01)

Patent

CA 2502395

A measurement device is provided for determining the oxygen activity in molten metal or slag with a measurement head, which is arranged on one end of a carrier tube and on which an electrochemical measurement cell is arranged. The electrochemical measurement cell has a solid electrolyte tubule, which is closed on one side and which contains on its closed end a reference material and an electrode, which projects from the opposite end of the solid electrolyte tubule. The solid electrolyte tubule has on its outer surface a coating made from a mixture of zirconium silicate with a fluoride. The measurement head may also have a thermo-element, and the device may be used to determine the concentration of silicon and/or carbon in the melt, based on the oxygen activity measurement.

Est présenté un dispositif de mesure servant à déterminer l'activité de l'oxygène dans une inclusion de métal en fusion ou une coulée de laitier à l'aide d'une tête de mesure, qui est fixée à une extrémité d'un tube porteur et qui porte une cellule de mesure électrochimique. La cellule de mesure électrochimique est munie d'un tubule d'électrolyte solide, qui est fermé d'un côté et qui contient une substance étalon et un électrolyte à son extrémité fermée, et se prolonge à partir de l'extrémité opposée du tubule d'électrolyte solide. Le tubule d'électrolyte solide est enduit sur sa surface extérieure d'un revêtement fait d'un mélange de silicate de zirconium et de fluorure. La tête de mesure peut aussi être munie d'un élément thermique, et le dispositif peut servir à déterminer la concentration de silicium et/ou de carbone dans le bain en fusion, en fonction de la mesure de l'activité de l'oxygène.

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