Measurement of specific dissolved gases

G - Physics – 01 – N

Patent

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G01N 7/04 (2006.01)

Patent

CA 2266567

A method and apparatus for the measurement of a specific dissolved gas in a liquid. The apparatus comprises a gas-permeable membrane for separation of dissolved gas from the liquid; a gas collecting chamber communicating with and disposed on the side of said membrane remote from the liquid for collecting dissolved gas separated from the liquid; a second chamber for receiving a gas absorbing or adsorbing material for the specific dissolved gas; means for interconnecting the second chamber to one gas collecting chamber to allow contact of the dissolved gas with the gas absorbing or adsorbing material; and pressure measuring means for providing a measurement of the difference of pressure of the gas resulting from the absorption or adsorption of the specific selected gas, thereby providing a measure of the quantity of the selected specific gas present in the liquid. The method involves interfacing the liquid to be measured with a gas-permeable membrane to allow permeation and separation of dissolved gas from the liquid, and confining separated gas to a chamber; establishing equilibrated pressure of the separated gas within the chamber representative of the sum of partial pressures of all dissolved gases; contacting the gas with a material that absorbs or adsorbs the specific selected gas to be measured, and determining the pressure reduction resulting from the absorption or adsorption of the specific selected gas, to provide a measure of the specific selected gas present in the liquid.

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