Melamine and guanamine-based crosslinking composition

C - Chemistry – Metallurgy – 08 – G

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Details

C08G 12/40 (2006.01) C08G 12/42 (2006.01) C09D 161/32 (2006.01)

Patent

CA 2519570

This invention relates to a crosslinking composition comprising a compound having the structure of Formula (I): where Z is a hydrogen, an alkyl of 1 to about 18 carbon atoms, an aryl of about 6 to about 24 carbon atoms, an aralkyl of about 7 to about 24 carbon atoms, or-NR2R2; each R2 is independently hydrogen, an alkyl, aryl or an aralkyl of 1 to about 18 carbon atoms or R3; where R3 is-CHROR1or (a) where R is alkyl, halogenated alkyl, aryl, aralkyl, halogenated aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; R1 is a hydrogen, alkyl, aryl, aralkyl, alkoxyalkyl or an alkaryl having from 1 to about 24 carbon atoms; and where the aalkyl or aryl groups in each radical may optionally have heteroatoms in their structure; B is a resifue of a poly(alkylaldehyde) with n aldehyde groups; n is an integer of 2 to about 4; and A is an amino moiety derived from the group consisting of guanamine and melamine. The above composition may be prepared by reacting a melamine or guanamine with a mono(alkylaldehyde), a poly(alkylaldehyde) and an alcohol.

La présente invention a trait à une composition de réticulation comportant un composé ayant la structure de formule (I). dans laquelle : Z est hydrogène, un alkyle de 1 à environ 18 atomes de carbone, un aryle d'environ 6 à environ 24 atomes de carbone, un aralkyle d'environ 7 à 24 atomes de carbone, ou -NR¿2?R¿2 ?; chaque R¿2? est indépendamment hydrogène, un alkyle, aryle ou un aralkyle de 1 à environ 18 atomes de carbone ou R¿3 ?; R¿3? est -CHROR¿1? ou (II) dans laquelle : R est alkyle, alkyle halogéné, aryle, aralkyle, aralkyle halogéné, alcoxyalkyle ou alkaryle ayant 1 à 24 atomes de carbone ; R¿1? est un hydrogène, alkyle, aryle, aralkyle, alcoxyalkyle ou un alkaryle ayant 1 à 24 atomes de carbones ; et où les groupes alkyle ou aryle dans chaque radical peut éventuellement comporte des hétéroatomes dans leur structure ; B est un résidu de poly(alkylaldéhyde) avec n groupes aldéhydes ; n est un nombre entier de 2 à environ 4 ; et A est un groupe fonctionnel aminé dérivé du groupe constitué de guanamine et de mélamine. Ladite composition peut être préparée par la réaction d'une mélamine ou d'une guanamine avec un mono(alkylaldéhyde), un poly(alkylaldéhyde) et un alcool.

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