Membrane cell operation

C - Chemistry – Metallurgy – 25 – B

Patent

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Details

C25B 13/00 (2006.01) C25B 1/26 (2006.01) C25B 1/46 (2006.01) C25B 15/00 (2006.01)

Patent

CA 2100483

The voltage requirements of a membrane-divided cell are decreased by operating the cell with a catholyte temperature significantly in excess of the anolyte temperature, generally at least 10°C greater and preferably at least 20°C greater. The invention is particularly useful in an electrochemical acidification process whereby aqueous sodium chlorate and sodium sesquisulfate solution is acidified for use in a chlorine dioxide generating process and aqueous sodium hydroxide is produced as a by-product.

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