Metal complexes of n-[n-(3,3-dimethylbutyl)...

C - Chemistry – Metallurgy – 07 – K

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C07K 5/06 (2006.01) A23L 1/236 (2006.01) C07K 5/072 (2006.01)

Patent

CA 2303433

Dipeptide sweeteners are disclosed that are metal complexes of N-[N-(3,3- dimethylbutyl)-L-.alpha.-aspartyl] -L-phenylalanine 1-methyl ester represented by formula (I) wherein Xp+ is selected from the group consisting of Al3+, Fe2+, Fe3+, Ca2+, Mg2+ and Zn2+; Yq- is selected from the group consisting of Cl-, SO42-, PO43- and CH3COO-; x is a number from 1 to 4 and pn=qm. Also disclosed is a liquid low-calorie sweetener containing such metal complexes.

L'invention concerne des édulcorants de type dipeptide qui sont des complexes métalliques de N-[N-(3,3-diméthylbutyl) -L-.alpha.-aspartyl] -L-phénylalanine 1-méthyl ester représentés par la formule ci-dessous. Dans cette formule, X?p+¿ est choisi parmi le groupe comprenant Al?3+¿, Fe?2+¿, Fe?3+¿, Ca?2+¿, Mg?2+¿ et Zn?2+¿; Y?q-¿ est choisi dans le groupe comprenant Cl?-¿, SO¿4??2-¿, PO¿4??3-¿ et CH¿3?COO?-¿; en outre, x est un nombre allant de 1 à 4 et pn=qm. L'invention concerne également un édulcorant liquide basses calories renfermant les complexes métalliques en question.

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