Metal oxides with improved resistance to reduction

B - Operations – Transporting – 01 – J

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B01J 20/00 (2006.01) C01F 7/02 (2006.01) C01G 3/02 (2006.01)

Patent

CA 2608584

Mixing small amounts of an inorganic halide, such as NaCl, to basic copper carbonate followed by calcination at a temperature sufficient to decompose the carbonate results in a significant improvement in resistance to reduction of the resulting copper oxide. The introduction of the halide can be also achieved during the precipitation of the carbonate precursor. These reduction resistant copper oxides can be in the form of composites with alumina and are especially useful for purification of gas or liquid streams containing hydrogen or other reducing agents.

L'invention concerne un procédé consistant à mélanger de petites quantités d'un halogénure inorganique, tel que NaCl, à du carbonate de cuivre basique, puis à calciner le mélange à une température suffisante pour décomposer le carbonate, ledit procédé permettant une amélioration significative de la résistance à la réduction de l'oxyde de cuivre en résultant. L'introduction de l'halogénure peut également être effectuée lors de la précipitation du précurseur du carbonate. Ces oxydes de cuivre résistants à la réduction peuvent se présenter sous forme de composites avec de l'alumine, et sont particulièrement utiles pour la purification de flux liquides ou gazeux contenant de l'hydrogène ou d'autres agents réducteurs.

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