Methane production

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 9/04 (2006.01) C07C 1/04 (2006.01) C10J 3/54 (2006.01)

Patent

CA 1046536

ABSTRACT OF THE DISCLOSURE Methane is produced by contacting a mixture of carbon monoxide or carbon dioxide and hydrogen with a carbon-alkali metal catalyst at a temperature in the range between about 500° F and about 1500° F and at a pressure between about atmospheric and about 2000 psig. The catalyst employed may be prepared by heating an intimate mixture of coal, coal char, coke or other carbonaceous solids and an alkali metal salt, hydroxide or similar constituent. Such a catalyst promotes the methanation of carbon monoxide and carbon dioxide and the formation of higher hydrocarbons by the Fincher-Tropach reaction and at the sametime is resistant to high temperature sintering and poisoning by sulfur compounds present in the feed gas. The catalyst can be regenerated if necessary by air oxidation.

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