Methanol homologation using cobalt-ruthenium catalysts

Details Methanol homologation using cobalt-ruthenium catalysts Methanol homologation using cobalt-ruthenium catalysts

C - Chemistry, Metallurgy

07

C

260/639, 260/572

C07C 31/08 (2006.01) B01J 23/20 (2006.01) B01J 23/24 (2006.01) C07C 29/32 (2006.01) C07C 45/49 (2006.01) C07C 47/06 (2006.01)

Patent

CA 1143748

ABSTRACT OF THE DISCLOSURE Methanol can be selectively converted to acetal- dehyde, ethanol or mixtures thereof, using a homogeneous process. The process comprises contacting methanol with carbon monoxide and hydrogen in the presence of a catalytic system containing cobalt-ruthenium complexes or a soluble ruthenium compound plus Co2(CO)8-n where n is from 0 to 4.

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