Methanol homologation using iron-cobalt catalyst

Details Methanol homologation using iron-cobalt catalyst Methanol homologation using iron-cobalt catalyst

C - Chemistry, Metallurgy

07

C

260/639, 260/495

C07C 31/08 (2006.01) B01J 31/20 (2006.01) C07C 29/32 (2006.01) C07C 45/49 (2006.01) C07C 47/07 (2006.01) C07C 69/14 (2006.01)

Patent

CA 1156258

ABSTRACT OF THE DISCLOSURE A homogeneous catalytic process for the homologa- tion of methanol to methyl acetate or methanol to ethanol, acetaldehyde or mixtures thereof. The process comprises reacting methanol with CO to yield methyl acetate or methanol with CO and H2 to yield ethanol, acetaldehyde or mixtures thereof in the presence of a catalytically effective amount of an iron-cobalt carbonyl cluster complex and an iodide promoter at temperatures of from about 100 to 250-C and pressures of about 5 to 100 MPa.

360805

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