Method and apparatus for acheiving high reaction rates in...

B - Operations – Transporting – 01 – D

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B01D 53/04 (2006.01) B01D 53/34 (2006.01) B01J 8/02 (2006.01) C09K 5/04 (2006.01) F25B 17/08 (2006.01) F25B 35/04 (2006.01) F28D 20/00 (2006.01)

Patent

CA 2049022

Reaction rates in chemisorption reactions involving solid reactants and gaseous ligands are improved by a process for maintaining optimized density of the solid reactant and/or reaction product by limiting to volumetric expansion thereof during the reaction. An apparatus for carrying out the process comprises one or more reaction chambers having volumetric expansion control means in the form of porous walls (10) and reactant support surfaces (12), either or both of which may be movable and biased, for maintaining contact with solid reactant and reaction products and restricting the volumetric expansion thereof during the chemisorption reaction. A suitable heat exchange fluid passes along the interior (16) of heat transfer tube (14).

Les taux de réaction de chimiosorption impliquant des agents de réaction solides et des ligands gazeux sont améliorés à l'aide d'un procédé qui maintient une densité optimalisée de l'agent de réaction solide et/ou du produit de réaction en limitant son expansion volumétrique pendant la réaction. Un appareil de mise en oeuvre du procédé comprend une ou plusieurs chambres de réaction ayant des moyens de commande de l'expansion volumétrique se présentant sous la forme de parois poreuses (10) et de surfaces (12) de support de l'agent de réaction, les parois ou les surfaces ou encore les deux pouvant être mobiles et biaisées pour maintenir le contact avec l'agent de réaction solide et les produits de réaction et restreindre leur expansion volumétrique pendant la réaction de chimiosorption. Un fluide d'échange thermique approprié passe le long de l'intérieur (16) du tube de transfert de chaleur (14).

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