Method and catalyst for direct sulphur oxidation of h2s...

C - Chemistry – Metallurgy – 01 – B

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C01B 17/04 (2006.01) B01D 53/52 (2006.01) B01D 53/86 (2006.01) B01J 27/04 (2006.01) B01J 27/30 (2006.01) B01J 38/04 (2006.01)

Patent

CA 2282668

The invention concerns a method wherein the H2S of a gas to be treated is sulphur oxidised by being contacted with an oxidation catalyst consisting of at least one oxysulphide of a metal selected among Ni, Fe, Co, Cu, Cr, Mo and W, associated with a silicon carbide support, by operating at temperatures lower than the dew point of the sulphur formed and more particularly ranging between 30 DEG C and 70 DEG C: The invention is useful for eliminating H2S contained in gases of various origins with recuperation of said H2S essentially in the form of sulphur.

L'H2S du gaz à traiter est oxydé en soufre au contact d'un catalyseur d'oxydation consistant en au moins un oxysulfure d'un métal choisi parmi Ni, Fe, Co, Cu, Cr, Mo et W, associé à un support en carbure de silicium, en opérant à des températures inférieures au point de rosée du soufre formé et plus particulièrement comprises entre 30 °C et 70 °C. Application à l'élimination de l'H2S contenu dans des gaz d'origines diverses avec récupération de cet H2S essentiellement sous la forme de soufre.

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