Method and catalyst for polymerizing a cationic...

C - Chemistry – Metallurgy – 07 – C

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252/117, 260/706

C07C 2/26 (2006.01) B01J 31/14 (2006.01) C07C 2/30 (2006.01) C10G 50/02 (2006.01)

Patent

CA 1213878

ABSTRACT Disclosed is a process for polymerizing cationically polymeriz- able monomers comprising: (A) providing a solution containing an activated catalyst, said catalyst comprising (a) an aluminum compound having the formula RnAlX3-n, wherein n is an integer from 0 to 3; R is C1-C12 alkyl, C7-C9 aralkyl, C7-C18 alkaryl or C6-C10 aryl; and X is C1, Br or I; and (b) (1) a compound having the formula R'X, wherein X is C1, Br or I and R' is C1-C24 alkyl, C3-C20 al- kenyl, C5-C9 bridged or non-bridged cycloalkyl or cycloalkenyl, C7-C9 aralkyl or (2) a hydrocarbon polymer carrying at least one X substituent wherein X is C1, Br or I; and (B) contacting cationically polymerizable monomers with the solution of activated catalyst of (A).

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