Method and compositions for inhibiting formation of...

E - Fixed Constructions – 21 – B

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E21B 37/06 (2006.01) C09K 8/52 (2006.01)

Patent

CA 2497366

A method for inhibiting formation of hydrocarbon hydrates in mixtures of water and a hydrate-forming guest molecule has been discovered that involves adding a composition to the mixtures in an amount that is effective in inhibiting formation of the hydrocarbon hydrates under conditions otherwise effective to form the hydrocarbon hydrates in the absence of the reaction product. The composition includes at least one dendrimeric compound having a number average molecular weight of at least 1,000 atomic mass units (amu); and at least one small molecular weight species having less than 1,000 amu, selected from the group consisting of polyalkyleneimine, polyallylamine, starch, sugars, and polymers or copolymers of vinyl alcohol or allyl alcohol; and, optionally, at least one surfactant.

L'invention concerne un procédé empêchant la formation d'hydrates d'hydrocarbures dans des mélanges d'eau et de molécule invitée formant un hydrate, consistant à ajouter une composition à ces mélanges, dans une quantité empêchant efficacement la formation d'hydrates d'hydrocarbures dans des conditions qui dans le cas contraire favorisent la formation d'hydrates d'hydrocarbures en l'absence du produit de réaction. La composition comprend au moins un composé dendrimère, de poids moléculaire moyen en nombre d'au moins 1000 unités de masse atomique (uma), et au moins une espèce de faible poids moléculaire, de poids moléculaire inférieur à 1000 uma, sélectionnés parmi le groupe comprenant polyalkylèneimine, polyallylamine, amidon, sucres et polymères et copolymères d'alcool vinylique ou allylique, et, éventuellement, au moins un tensioactif.

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