Method and electrocatalyst for making chlorine dioxide

C - Chemistry – Metallurgy – 25 – B

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C25B 1/26 (2006.01) C25B 11/04 (2006.01)

Patent

CA 1198077

ABSTRACT This invention is directed to an electrocatalytic process for making chlorine dioxide from a strong acid and a metal chlorate solution wherein the catalyst com- prises a platinum group metal oxide mixture selected from the following metal combinations: ruthenium and rhodium; ruthenium and palladium; iridium and rhodium; iridium and platinum; rhodium and palladium; and ruthenium, rhodium and palladium, each constituent of said mixture being present in a mole ratio of not less than 0.01. The combined feedstock contains sulphuric acid or phosphoric acid and a chlorate of an alkali metal or alkaline earth metal.

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