Method for adjusting the coagulation point of carboxylated...

C - Chemistry – Metallurgy – 08 – F

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C08F 2/26 (2006.01) C08C 1/14 (2006.01) C08F 212/08 (2006.01) C08F 236/10 (2006.01) C08F 236/12 (2006.01) C08K 5/00 (2006.01) C08L 9/08 (2006.01) C08L 25/10 (2006.01)

Patent

CA 1068028

METHOD FOR ADJUSTING THE COAGULATION POINT OF CARBOXYLATED LATICES Abstract of the Disclosure Process for reducing the coagulation point of a rubber la- tex which is free from non-ionogenic emulsifiers and contains the following components in polymerised form: 1) 20 - 60 parts by weight of styrene, 2) 40 - 80 parts by weight of butadiene, 3) 1 - 6 parts by weight of acrylic acid and/or methacrylic acid, 4) 0 - 15 parts by weight of acrylonitrile and/or methacrylo- nitrile, 5) 0 - 5 parts by weight of acrylamide and/or methacrylamide and 6) 0 - 5 parts by weight of N-hydroxymethyl- and/or N-alkoxyme- thyl-acrylamide and/or -methacrylamide, in which the sum of components 5 and 6 must be at least 1 part by weight, wherein only anionogenic emulsifiers of the kind which can easily be biologically degraded are used in the preparation of the latex and the quantity of components 4, 5 and 6 is calcula- ted so that after the addition of a heat sensitizing agent to the latex a coagulation point of 35 to 60°C which remains constant over a prolonged period is obtained.

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