Method for ammoxidation of paraffins and catalyst system...

C - Chemistry – Metallurgy – 07 – C

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252/52.J, 260/56

C07C 253/24 (2006.01) B01J 23/18 (2006.01) B01J 23/22 (2006.01) B01J 23/28 (2006.01) B01J 23/84 (2006.01) B01J 27/198 (2006.01) B01J 37/04 (2006.01) C07C 255/08 (2006.01)

Patent

CA 1305121

CSL-P-1376B ABSTRACT Ammoxidation of C3 to C5 acyclic alkanes with NH3 and O2 using (1) a mole ratio of alkane:NH3 in the range from 2 to 16 and a mole ratio of alkane:O2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed. 6-MAY-87

563884

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