Method for carrying out heterogeneous catalysis

C - Chemistry – Metallurgy – 07 – C

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C07C 27/06 (2006.01) B01D 3/00 (2006.01) B01J 8/02 (2006.01) B01J 8/22 (2006.01) B01J 10/00 (2006.01) C07C 29/151 (2006.01)

Patent

CA 2301690

Catalytic distillation reactions are improved by having an inert condensing component present in the reaction which is boiling and condensing within the reaction which washes the catalyst in the system and, in the case of gaseous reactants, occludes a portion of the reactants to facilitate the reaction without unduly high pressures. The inert condensing component is boiling at the conditions within the reactor and is taken overhead for condensation and return as reflux. The inert condensing component may occlude the gaseous reactants allowing for better contact with the catalyst and provides the benefits of concurrent reaction and distillation, for example, the reaction of CO and H2 over a copper catalyst to produce methanol using propane as the inert condensing component.

On améliore des réactions de distillation catalytique du fait de la présence dans la réaction d'un constituant condensateur inerte qui bout et se condense dans la réaction, ce qui lave le catalyseur dans le système et, en cas de réactifs gazeux, qui enferme une partie des réactifs pour faciliter la réaction sans pressions indûment élevées. Le constituant condensateur inerte bout aux conditions internes du réacteur et est pris comme produit de tête pour la condensation et le retour en tant que reflux. Ledit constituant peut enfermer les réactifs gazeux, ce qui permet un meilleur contact avec le catalyseur et fournit l'avantage d'une réaction et d'une distillation concomitantes, par exemple la réaction de CO et de H2 sur un catalyseur de cuivre pour produire du méthanol à l'aide de propane en tant que constituant condensateur inerte.

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