Method for commercial preparation of conjugated linoleic...

C - Chemistry – Metallurgy – 11 – C

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C11C 3/14 (2006.01) C07C 51/353 (2006.01) C07C 57/12 (2006.01) C11C 1/08 (2006.01) C11C 3/06 (2006.01)

Patent

CA 2466911

Conjugated linoleic acid is readily prepared by mixing crude alkaline glycerol solution derived as a byproduct of triglyceride transesterification and a linoleate rich triglyceride, ester, soap, phospholipid, fatty acid, or wax and heating the mixture sufficiently to conjugate the linoleate double bonds. The reaction produces a favourable isomer mixture enriched in 10, 12-trans,cis octadecadienoic and 9,11- cis, trans-octadecadienoic acids.

Procédé de préparation aisée d'acide linoléique conjugué qui comporte les étapes consistant à : mélanger une solution alcaline de glycérol brut obtenue comme sous-produit de la transestérification de triglycérides et d'un triglycéride, d'un ester, de savon, d'un phospholipide, d'un acide gras ou de cire riches en linoléate ; chauffer suffisamment le mélange pour conjuguer les doubles liaisons de linoléate. Cette réaction permet d'obtenir un mélange d'isomères favorable enrichi en acides 10,12-trans,cis octadécadiénoïque et 9,11-cis,trans octadécadiénoïque.

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