Method for electrochemical production of ni(0) phosphite and...

C - Chemistry – Metallurgy – 07 – F

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C07F 15/04 (2006.01) B01J 31/18 (2006.01) B01J 37/34 (2006.01) C07C 253/10 (2006.01)

Patent

CA 2376294

Method for electrochemical production of phosphite and diphosphite Ni(0) complexes in a diaphragmless electrolyzer, containing an anode and cathode, by anode dissolution of metallic nickel in an aprotic solvent with subsequent electroreduction of nickel ions on the cathode with low hydrogen overvoltage in the presence of, for example, an equimolar amount, of phosphorus ligands, using direct or alternating current. The complexes are useful as catalysts.

L'invention concerne un procédé de production électrochimique de complexes de phosphite et de diphosphite Ni(0), dans un électrolyseur sans membrane qui comporte une anode et une cathode. Ce procédé consiste à dissoudre une anode de nickel métallique dans un solvent aprotique, avec électroréduction subséquente d'ions nickel sur la cathode, avec une surtension d'hydrogène basse, par exemple, en présence d'une quantité équimolaire de ligands de phosphore, en utilisant un courant continu ou alternatif. Les complexes servent de catalystes.

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