Method for forming new preceramic polymers for sic and...

C - Chemistry – Metallurgy – 08 – L

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402/10, 261/41

C08L 83/10 (2006.01) C08G 77/60 (2006.01) C08L 83/16 (2006.01)

Patent

CA 1263797

ABSTRACT OF THE DISCLOSURE A method of forming preceramic polymers using an organosilicon polymers containing Si-H repeat units by reacting it with alkali metal silylamids is disclosed. Preferably, the alkali metal silylamide is a polymeric alkali metal silylamide of the formula [(R1SiHNH)a(R1SiN)b(R1SiHNM)c]m (where a + b + c = 1; R1 is a lower alkyl group having from 1 to about 6 carbon atoms, a substituted or unsubstituted alkenyl group having from 2 to about 6 carbon atoms, a substituted or unsubstituted lower aryl group having from 6 to about 10 carbon atoms, a tri(lower)alkyl- or di(lower)alkylsilyl group or a di(lower)alkylamino group; M is an alkali metal or one-half equivalent of an alkaline earth metal; and n and m are integers greater than 1). The Si-H containing organosilicon polymer is preferably selected from the group consisting of organopolysilanes of the formula [(RSiH)x(RSi)y]n (where R is a lower alkyl group having from 1 to about 6 carbon atoms, a lower alkenyl group having from 2 to about 6 carbon atoms, or a substituted or unsubstituted lower aryl group having from 6 to about 10 carbon atoms, and n is greater than 1), and polycarbosilanes having repeat units of the formula [RaSi(H)-(CH2)q] (where Ra is H, a lower alkyl group having from 1 to about 6 carbon atoms, a cycloalkyl group having from 3 to about 6 carbon atoms, or a substituted or unsubstituted lower aryl group having from 6 to about 10 carbon atoms, q is an integer 1 or greater). Novel preceramic polymers formed by this method are also disclosed.

514060

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