Method for fractionation of lignins from steam exploded...

D - Textiles – Paper – 21 – B

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D21B 1/36 (2006.01) D21C 3/02 (2006.01) D21C 3/04 (2006.01) D21C 3/20 (2006.01) C07G 1/00 (2006.01) C08H 6/00 (2010.01)

Patent

CA 1278294

Abstract The chemical components of lignocellulosic material which have been dissociated by a steam explosion process can be extracted from the mixture of components using a solvent extraction process. The solvents are water, alcohol and a mild caustic in that order, or the alcohol step can be by-passed and only water and caustic are used. The caustic is a stronger solvent and it will extract the alcohol solubles along with the caustic only solubles. The eluant from the these extractions contains a range of lignin derived substances, which have different applications, such as thermoplastic and thermosetting characteristics. This invention describes a method for partitioning these lignin components into reproducible fractions having definable characteristics for particular applications. For instance, many copolymer applications require a thermosetting only fraction of the lignin. Other applications require a thermoplastic only lignin. The patent also describes a process for converting the thermoplastic lignin fraction to thermosetting lignin.

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