Method for hydrogenating aliphatic alpha-, omega-dinitriles

C - Chemistry – Metallurgy – 07 – C

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C07C 209/48 (2006.01) B01J 23/02 (2006.01) B01J 23/78 (2006.01) C07C 211/12 (2006.01) C07C 253/30 (2006.01) C07C 255/24 (2006.01)

Patent

CA 2322530

The invention relates to a method for hydrogenating aliphatic alpha-, omega- dinitriles in the presence of a heterogeneous fixed-bed catalyst. The method is characterised in that the reaction mixture contains 2 µmol to 30 mmol Na, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, in relation to 10 mol of the aliphatic alpha-, omega-dinitrile used.

L'invention concerne un procédé d'hydrogénation de dinitriles alpha,oméga aliphatiques en présence d'un catalyseur en lit fixe hétérogène. Ce procédé est caractérisé en ce que le mélange réactionnel contient 2 µmol à 30 mmol de Na, K, Rb, Cs, Mg, Ca, Sr, Ba ou Mn ou de leurs mélanges sous forme de sel basique par rapport à 10 mol des dinitriles alpha, oméga aliphatiques utilisés.

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