Method for making a chlorohydrin by chlorinating a...

C - Chemistry – Metallurgy – 07 – C

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C07C 29/62 (2006.01) A62D 3/00 (2007.01) C07C 29/88 (2006.01) C07C 31/36 (2006.01) C07C 31/42 (2006.01)

Patent

CA 2608953

The invention concerns a method for making a chlorohydrin including the following steps: (a) reacting a polyhydroxylated aliphatic hydrocarbon, an ester of a polyhydroxylated aliphatic hydrocarbon, or a mixture thereof, whereof the alkali and/or alkaline-earth metal content is not more than 5g/kg, an oxidizing agent and an organic acid to obtain a mixture containing at least chlorohydrin and by-products; (b) subjecting at least part of the mixture obtained at step (a) to one or more treatments in steps subsequent to step (a); oxidizing at a temperature not less than 800 ~C at least at one of the steps subsequent to step (a).

Procédé de fabrication d'une chlorhydrine comprenant les étapes suivantes : (a) on fait réagir un hydrocarbure aliphatique poly hydroxylé, un ester d'un hydrocarbure aliphatique poly hydroxylé, ou un mélange d'entre eux, dont la teneur en métaux alcalins et/ou alcalino-terreux est inférieure ou égale à 5 g/kg, un agent oxydant et un acide organique de façon à obtenir un mélange contenant au moins de la chlorhydrine et des sous-produits (b) on soumet au moins une partie du mélange obtenu à l'étape (a) à un ou plusieurs traitements dans des étapes ultérieures à l'étape (a) (c) on oxyde à une température supérieure ou égale à 800 °C à au moins une des étapes ultérieures à l'étape (a).

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