Method for making and using a supported metallocene catalyst...

C - Chemistry – Metallurgy – 08 – F

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C08F 4/622 (2006.01) C07F 17/00 (2006.01) C08F 10/00 (2006.01) C08F 10/02 (2006.01) C08J 5/18 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01) C08F 110/02 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2143586

Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in a suitable liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.

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