Method for making industrial chemicals

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 11/02 (2006.01) C07C 1/213 (2006.01) C07C 6/02 (2006.01) C07C 6/04 (2006.01) C12P 5/02 (2006.01)

Patent

CA 2512815

A process for producing industrially important chemicals from renewable resources is disclosed. This "biobased" process employs readily available, renewable resources comprising fatty acids rather than exploiting fossil sources, such as coal and petroleum. In one embodiment of the process 1- octene, along with methyl-9-decenoate and butadiene, is produced from linoleic acid via an enzyme~mediated isomerization reaction, followed by a metathesis reaction with ethylene. Linoleic acid can be isolated from vegetable oils, such as soybean oil.

Cette invention concerne un procédé de production de produits chimiques d'intérêt industriel à partir de ressources renouvelables. Ce procédé dit biologique fait appel à des ressources renouvelables immédiatement disponibles, telles que des acides gras, plutôt qu'à l'exploitation de sources fossiles, telles que le charbon ou le pétrole. Dans un mode de réalisation de cette invention, ce procédé consiste à produire du 1-octène de même que du méthyl-9-décénoate et du butadiène à partir d'acide linoléique au moyen d'une réaction d'isomérisation induite par une enzyme, suivie d'une réaction de métathèse utilisant de l'éthylène. L'acide linoléique peut être isolé à partir d'huiles végétales, telles que l'huile de soja.

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