Method for making polyethylene glycol carbonates

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 64/28 (2006.01) C08G 64/30 (2006.01) A61K 47/48 (2006.01)

Patent

CA 2656693

A method for making an alkyl polyethylene glycol carbonate by the step of reacting mono-alkyl polyethylene glycol (mPEG) such as mPEG having an average molecular weight of 20,000 grams. Per mole and a polydispersity of less than 1.1, a chloro formate such as p-nitrophenyl chloroformate, an aromatic solvent such as toluene and an amine such as tripentylamine. And, a method for making a multi-armed polyethylene glycol carbonate by the step of reacting a multi-armed polyethylene glycol having at least one hydroxyl group, a chloroformate, an aromatic solvent and an amine.

La présente invention concerne une méthode de fabrication d'un carbonate d'alkylpolyéthylène glycol par une étape de réaction d'un mono-alkylpolyéthylène glycol (mPEG) tel qu'un mPEG de masse moléculaire moyenne égale à 20 000 grammes par mole et de polydispersion inférieure à 1,1, d'un chloroformiate tel que le chloroformiate de p-nitrophényle, d'un solvant aromatique tel que le toluène et d'une amine telle que la tripentylamine. La présente invention concerne également une méthode de fabrication d'un carbonate de polyéthylène glycol ramifié par l'étape de réaction d'un polyéthylène glycol ramifié portant au moins un groupement hydroxy, d'un chloroformiate, d'un solvant aromatique et d'une amine.

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