Method for manufacturing pyridine and pyridine derivatives...

C - Chemistry – Metallurgy – 07 – D

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260/295, 260/425

C07D 213/08 (2006.01) C07D 213/73 (2006.01) C07F 15/06 (2006.01)

Patent

CA 1156237

ABSTRACT OF DISCLOSURE The preparation of pyridine and pyridine derivatives from alkynes and cyano compounds including HCN is disclosed. The process can be carried out in the presence of a cobalt or rhodium catalyst having at least one ligand with one or more boron atoms. Certain new cobalt or rhodium catalysts containing such ligand are also disclosed. Also disclosed is a process for the formation of 2-aminopyridine by contacting acetylene with cyanamide such as in the presence of a cobalt or rhodium catalyst which has at least one ligand with one or more boron atoms.

402066

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