Method for preparing aluminosilicates, their use as catalyst...

B - Operations – Transporting – 01 – J

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252/12, 252/3

B01J 29/06 (2006.01) B01J 29/40 (2006.01) B01J 31/02 (2006.01)

Patent

CA 1115259

ABSTRACT Aluminosilicates containing an organic nitrogen cation are prepared by mixing sources of silica, alumina and an alkali metal, water and either mono-ethanolamine or mono-propanolamine, or a derivative, or the precursors or a combination thereof and maintaining the mixture at a temperature in the range from 80 to 210°C and a pressure in the range from 70 to 400 psig for over 4 hours. In a preferred embodiment the alkanolamines are prepared 'in situ' by reaction of the corresponding alkylene oxide with ammonia. Aluminosilicates so-prepared can be used without modification as catalysts and catalyst supports. Catalytic activity can be enhanced by, for example, reduced the sodium content or impregnating with a compound of one or more metals belonging to Groups 1B, 11B, 111A, 1VA, VA and V111 or reaction with a compound of one or more non- metals of Group 111A and VA of the Periodic Table.

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