Method for preparing aromatic carboxylic acids

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

C07C 63/38 (2006.01) C07C 51/255 (2006.01) C07C 51/265 (2006.01) C07C 51/487 (2006.01) C07C 63/15 (2006.01)

Patent

CA 2115451

2115451 9400413 PCTABS00030 Disclosed is a method for preparing an aromatic carboxylic acid comprising oxidizing in the liquid phase an aromatic feed compound containing at least one alkyl or acyl group with a molecular oxygen-containing gas, in a solvent comprising a low molecular weight aliphatic carboxylic acid, and in the presence of a heavy metal oxidation catalyst, thereby forming an oxidation reaction product mixture comprising an aromatic carboxylic acid; subsequently heating the oxidation reaction product mixture at a temperature of at least about 500 ·F (260 ·C) to form a second product mixture; and recovering from the second product mixture the aromatic carboxylic acid. The method of this invention provides for purer, larger particle size aromatic carboxylic acid product.

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