Method for preparing dual colloid catalyst compositions

Details Method for preparing dual colloid catalyst compositions Method for preparing dual colloid catalyst compositions

B - Operations, Transporting

01

J

23/221, 252/52.L

B01J 37/02 (2006.01) B01J 23/74 (2006.01) B01J 23/78 (2006.01) B01J 23/89 (2006.01) B01J 35/00 (2006.01) B01J 35/10 (2006.01) B01J 37/03 (2006.01)

Patent

CA 1250565

ABSTRACT OF THE DISCLOSURE Disclosed herein are catalyst compositions and preparation, which catalyst compositions are comprised of: (a) from about 15 to about 85 wt.% of crystallites selected from the group consisting of (i) crystallites of one or more transition metals and (ii) crystallites of reducible transition metal carbides and nitrides, and mixtures thereof, said transition metal being selected from those reducible metals from Groups IB, IIB, VIB, VIIB, and VIII of the Periodic Table of the Elements, wherein at least 80% of the crystallites have a diameter, d, between about 25.ANG. and 500.ANG. with the proviso that the crystallite size distribution of at least about 80% of these be expressed by the relationship 0.5D<d<2D where D is the median of the diameters of this 80%. (b) from about 15 to about 85% wt.% of a nonreducible promoter phase interdispersed with the metal crystallites and containing at least one element selected from the group consisting of Cr, Al, Si, Th, U and lanthanides, and Group IA, IIA, IIIB, IVB, and VB of the Periodic Table of the Elements, wherein the promoter phase is comprised of particles of which at least about 80% have a diameter between about 15.ANG. and 1500.ANG. wherein the median diameter (D) of the metal crystallites and the median diameter of the 80% of the promoter particles do not differ by more than a factor of 20.

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